The problem with acrylic is that it scratches very easily, so if you have a lot of algae growing on it, don't try to remove them with a scouring pad. Use soft sponges only and put some elbow grease into it. Any cleaning fluid will do to remove the brunt of the mess (washing-up liquid, diluted bleach, etc ...) and then, if you want a "sparkling finish"

, you can give a final rinse with a window cleaner. I personally don't bother with the window cleaning stuff and prefer to use washing-up liquid first and then diluted bleach in the hope it will disinfect the windows and retard the algae from reappearing. A lot of algae on your windows is a good sign though, it means your greenhouse is nice and humid. If the windows of a greenhouse remain clean after a full year of growing orchids, then there's definitely not enough humidity in there.